It Buster's day off so Rio meets up with him at her lunch hour. Planning to unwind since there's a big conference going on at work, thing is she was followed.

This is Jolene; she's the top model at the agency Rio works at. She's also the reason Rio ended up behind a desk instead of in front of a camera. When Rio auditioned Jolene knew she would have become more popular than herself so she used her position to stop Rio from getting the job.
However Rio was too good to let a rival company to get a hold of and smart enough to work a desk so they gave a P.R. job instead.
Jolene still goes out of her way to make Rio's life hell and steeling Buster would make her day.

The song is Megadeth's Shewolf.

The mother of all that is evil
Her lips are poisonous venom
Wicked temptress knows how to please
The priestess roars, get down on your knees
The rite of the praying mantis
Kiss the bones of the enchantress
Spellbound searching through the night
A howling man surrenders the fight

One look in her lusting eyes
Savage fear in you will rise
Teeth of terror sinking in
The bite of the she-wolf

My desires of flesh obey me
The lioness will enslave me
Another heart beat than my own
The sound of claws on cobblestone, Im stoned

Beware what stalks you in the night
Beware the she-wolf and her bite
Her mystic lips tell only lies
Her hidden will to kill in disguise

1. Her Name is Rio... [link]
2. Foxy Lady [link]
3. Wig Wam Bam [link]
4. Nine to Five [link]
5. Young Lust [link]
6. Mr Jones [link]
7. Moondance [link]
8. FACT This is Rio's favorite cafe.